Brushed stainless steel has a more matte finish and is less reflective. Whilst polished stainless steel has a mirror-like finish.
In general, polished stainless steel will be more durable and resistant to tarnishing and corrosion. This is because it will have a smaller surface area in comparison to brushed stainless steel. Often, impurities & dirt can get trapped within the small gaps on brushed stainless steel, causing it to degrade at a much faster rate.
Whether brushed or polished stainless steel jewellery is better for you will depend mostly on your preferences in regards to appearance.
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